It was discovered by Heike Kamerlingh Onnes in 1911. Like ferromagnetism and atomic spectral lines, superconductivity is a quantum mechanical phenomenon. It cannot be understood simply as the idealization of "perfect conductivity" in classical physics.
For instance, all superconductors have exactly zero resistivity to low applied currents when there is no magnetic field present. The existence of these "universal" properties implies that superconductivity is a thermodynamic phase, and thus possess certain distinguishing properties which are largely independent of microscopic details.
This is called the Meissner effect , and is a defining characteristic of superconductivity. For most superconductors, the London penetration depth is on the order of 100 nm.
Superconductors can be divided into two classes according to how this breakdown occurs. In Type I superconductors, superconductivity is abruptly destroyed when the strength of the applied field rises above a critical value H c . Depending on the geometry of the sample, one may obtain an intermediate state consisting of regions of normal material carrying a magnetic field mixed with regions of superconducting material containing no field. In Type II superconductors, raising the applied field past a critical value H c 1 leads to a mixed state in which an increasing amount of magnetic flux penetrates the material, but there remains no resistance to the flow of electrical current as long as the current is not too large. At a second critical field strength H c 2 , superconductivity is destroyed. The mixed state is actually caused by vortices in the electronic superfluid, sometimes called fluxons because the flux carried by these vortices is quantized. Most pure elemental superconductors, except niobium, technetium, vanadium and carbon nanotubes, are Type I, while almost all impure and compound superconductors are Type II.
Source: Wikipedia > Superconductivity
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